ATOMIC SPECTROSCOPY
measures transitions between the electronic energy levels of
(metal) atoms
Spectroscopy normally implies that a spectrum of
absorption or emission versus
wavelength (or frequency) is obtained at a
fixed concentration.
Spectrometry usually measures absorption (or emission)
at a single wavelength (frequency) over a range of concentrations.
- turns the sample into atoms and measures photons emitted or absorbedas a result of
transition of an electron between energy levels
atomic emission - creates colours when metallic salts are burned in flames
flame photometry - samples dissolved in a solvent are volatilised and sprayed into a flame.
- depends on being able to create a significant population in the excited states
- difficult at flame temperatures.
- widely used in the analysis of blood found coupled with more complicated excitation sources such as plasmas